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Provides a basic introduction to frontier orbital theory with a review of its applications in organic chemistry. Assuming the reader is familiar with the concept of molecular orbital as a linear combination of atomic orbitals the book is presented in a simple style, without mathematics making it accessible to readers of all levels.
- Sales Rank: #1055549 in Books
- Published on: 1991-01-15
- Original language: English
- Number of items: 1
- Dimensions: 9.00" h x .58" w x 6.02" l, .0 pounds
- Binding: Paperback
- 249 pages
From the Back Cover
This book is both a simplified account of frontier orbital theory and a review of its applications in organic chemistry; it provides a basic introduction to the subject and a wealth of illustrative examples. Frontier orbital theory looks at how the transition state of an organic reaction is affected by the interaction of the molecular orbitals of the starting materials. It thus complements the more familiar thermodynamic picture of transition states, in which product-like character is seen as influencing the ease and the course of reactions. The theory is presented very simply, without mathematics, stressing physical principles and assuming only that the reader is familiar with the concept of a molecular orbital as a linear combination of atomic orbitals. This book thus makes frontier orbital theory accessible for the first time to readers at every level. Contents Introduction; Molecular Orbitals and Frontier Orbitals; Ionic Reactions; Thermal Pericyclic Reactions; Radical Reactions; Photochemical Reactions; Exceptions.
About the Author
IAN FLEMINGstudied in Cambridge, obtaining his BA in 1959 and PhD (with Dr J Harley-Mason) in 1962. He spent one year at Harvard University (with Professor RB Woodward) before returning to Cambridge, where he is now an Assistant Director of Research and a Fellow of Pembroke College. He was a Visiting Professor at McGill University in 1972. His research interests centre on synthetic organic chemistry and on understanding the mechanisms of chemical reactions.
Most helpful customer reviews
3 of 3 people found the following review helpful.
Excellent and in depth
By Tiffany Cline
For any chemistry major I cannot recommend this book enough. It is one of the musts to really understanding organic chemistry... and compared to the textbooks the exercises are... dare I say fun?
3 of 4 people found the following review helpful.
Even better than Moonraker
By Craig Girten
Fleming's science and mathematical texts are top-notch. My first exposure to his work was when I was given a copy of "Casino Royale," a book on casino probabilities and card-counting. While it was a little out of my field, learning about systems like High-Low as well as Effect of Removal definitely improved my understanding of on-the-fly statistical projections. A few years later, I read Moonraker for a course on orbital ballistics - this was much more my speed, and I learned a great deal about hyperbolic and parabolic trajectories. More recently, I read (mostly for recreational purposes) "Chitty Chitty Bang Bang," which, while aimed at a juvenile audience, still greatly enhanced my knowledge of internal combustion engines - hey, I'm a rocket surgeon, not a mechanical engineer. His most recent text, "Frontier Orbitals and Organic Chemical Reactions," while less imaginatively-named than his earlier works, still facilitated my understanding of peroxide-based liquid fuels and how to correctly predict outer-shell orbital interactions as well as electron pushing for that murky area between the organic and inorganic fields of chemistry, oxidation.
Highly recommended.
3 of 4 people found the following review helpful.
The FMO Bible
By A Customer
Provides an outstanding introduction to the concepts of molecular orbital interaction in organic chemistry. Presents the topic such that an organic chemist without a strong background in group theory or math can still follow the discussion.
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